研究・制作業績システム - 大嶋　正人

オオシマ　マサト OSHIMA Masato
大嶋　正人

所属東京工芸大学工学部工学科　化学・材料コース

職名教授

著書・論文歴
著書	化学大百科 (単著) 1991/04/01
著書	触媒の事典 (単著) 2000/04/01
著書	化学大百科朝倉書店、
著書	触媒の事典朝倉書店、
論文	Stereoselective Synthesis of (E) -5-Hydroxy-4-methyl-2-alkenoates by Palladium Catalyzed Stereospecific Hydrogenolysis of (E) -4_5-poxy-4-methyl-2-alkenoates with Ammonium Formate. Chem.Lett.,1775-75-6頁 1986/07/01
論文	STEREOSELECTIVE SYNTHESIS OF (E)-5-HYDROXY-4-METHYL-2-ALKENOATES BY PALLADIUM-CATALYZED STEREOSPECIFIC HYDROGENOLYSIS OF (E)-4,5-EPOXY-4-METHYL-2-ALKENOATES WITH AMMONIUM FORMATE (10),1775-1776頁 (共著) 1986/10/01
論文	STEREOSELECTIVE SYNTHESIS OF (E)-5-HYDROXY-4-METHYL-2-ALKENOATES BY PALLADIUM-CATALYZED STEREOSPECIFIC HYDROGENOLYSIS OF (E)-4,5-EPOXY-4-METHYL-2-ALKENOATES WITH AMMONIUM FORMATE 15 (10),1775-1776頁 (共著) 1986/10/01
論文	Development of highly selective synthetic methods based on catalytic reactions via ?-allylpalladium complexes and their applications to synthesis of biologically active substances. I. Synthesis of ?-fluoro ketones and ?-keto acids by de¬carboxy¬lation re 旭硝子工業技術奨励会-研究報告 Vol 55,251-256頁 1989/07/01
論文	Facile Synthesis of ?-Keto Acids and Esters by Palladium-Catalyzed De¬carboxy¬lation Reactions of Diallyl ?-Oxal¬carboxylates Chem.Lett.,1457-7-60頁 1989/07/01
論文	Palladium-Catalyzed Selective Hydrogenolysis of Alkenyloxirane with Formic Acid : Stereoselectivity and Synthetic Utility J.Am.Chem.Soc. Vol 111,1599946-1599946頁 1989/07/01
論文	FACILE SYNTHESIS OF ALPHA-KETO ACIDS AND ESTERS BY PALLADIUM-CATALYZED DECARBOXYLATION REACTIONS OF DIALLYL ALPHA-OXALCARBOXYLATES 18 (8),1457-1460頁 (共著) 1989/08/01
論文	PALLADIUM-CATALYZED SELECTIVE HYDROGENOLYSIS OF ALKENYLOXIRANES WITH FORMIC-ACID - STEREOSELECTIVITY AND SYNTHETIC UTILITY 111 (16),6280-6287頁 (共著) 1989/08/01
論文	A short stereoselective synthesis of (-)-serricornin 31 (33),4757-4758頁 (共著) 1990/04/01
論文	Development of highly selective synthetic methods based on catalytic reactions via ?-allylpalladium complexes and their applications to synthesis of biologically active substances. II. Stereo¬selective hydrogenolysis of alkenyloxiranes and its applicatio 旭硝子工業技術奨励会-研究報告 Vol 56,281-291頁 1990/07/01
論文	A Short Stereoselective Synthesis of (-) - Serricornin. Tetrahedron Lett. Vol 31,1043712-1043712頁 1991/03/01
論文	FACILE SYNTHESIS OF (-)-SERRICORNIN BY MEANS OF PALLADIUM-CATALYZED HYDROGENOLYSIS OF ALKENYLOXIRANES 47 (18-19),2991-2998頁 (共著) 1991/05/01
論文	ギ酸-パラジウム触媒系によるアリル化合物の加水分解反応:その有機合成への応用有機合成化学協会誌 49 (6),526-540頁 (共著) 1991/06/01
論文	Facile Synthesis of (-) - Serricornin by Means of Palladium Catalyzed Hydrogenolysis of Alkenyloxiranes Tetrahedron Vol 47,398694-398694頁 1991/07/01
論文	Palladium-catalyzed selective hydrogenolysis of alkenyl¬oxiranes with formic acid and its application to organic syntheses Mem. Sch. Sci. Eng._ Waseda Univ.,199-220頁 1991/07/01
論文	Synthesis and Properties of π-Allylpalladium Formates as Intermediate in Palladium-Catalyzed Reductive Cleavage of Allylic Acetates and Carbonates with Formic Acid. Organometallics Vol 10,1221-21-3頁 1991/07/01
論文	ギ酸-パラジウム触媒系によるアリル化合物の加水分解反応:その有機合成への応用有機合成化学協会誌 Vol 49,526-540頁 1991/07/01
論文	Facile Allylation of Ethyl 4_4_4-Trifluoroacetoacetate by Palladium Catalysis Synlett,301-1-2頁 1992/07/01
論文	Formation of Novel Trinuclear Ruthenium Alkoxo Complexes and Tetrameric Ruthenium Hydroxo Complex. Crystal Structure of [(5-C5Me5)¬Ru]3¬(3-O)¬(3-OiPr) and [(5-C5Me5)¬Ru(*3-OH)]4 Chem.Lett.,1707-1710頁 1993/07/01
論文	FORMATION OF NOVEL TRINUCLEAR RUTHENIUM ALKOXO COMPLEXES AND A TETRAMERIC RUTHENIUM HYDROXO COMPLEX - CRYSTAL-STRUCTURE OF [(ETA(5)-C-5ME(5))RU]3(MU(3)-O)(MU(3)-OIPR) AND [(ETA(5)-C-5ME(5))RU(MU(3)-OH)]4 Chemistry letters 1993 (10),1707-1710頁 (共著) 1993/10/01
論文	Synthesis and Structure Determination of Oxygen-Functionalized Ruthena cycle : Intramolecular Attack of Coordinated Hydroxide on an Acethylenic Ligand. Chem.Lett.,921-1-2頁 1995/07/01
論文	SYNTHESIS AND STRUCTURE DETERMINATION OF AN OXYGEN-FUNCTIONALIZED RUTHENACYCLE - INTRAMOLECULAR ATTACK OF COORDINATED HYDROXIDE ON AN ACETYLENIC LIGAND 1995 (10),921-922頁 (共著) 1995/10/01
論文	Synthesis and properties of (eta(3)-1-methylallyl)palladium(II) formates as models of intermediates in the palladium-catalyzed reductive cleavage of allylic carboxylates and carbonates with formic acid Bulletin of the Chemical Society of Japan 73 (2),453-464頁 (共著) 2000/02/01
論文	Synthesis and Properties of (?3-1-Methylallyl)palladium(II) Formates as Models of Intermediates in the Palladium-Catalyzed Reductive Cleavage of Allylic Carboxylates and Carbonates with Formic Acid Bull. Chem. Soc. jpn. Vol 77,453-464頁 2000/07/01
論文	Novel Trinuclear trihydride Complexes of Ruthenium Having a Triply Bridging Borylene Ligand_ {?5-C5Me5}Ru}3(?-H)3(?3-BX) (X = H_ CN_ OMe_ OEt). Synthesis_ Structure Determination_ and Reaction with Benzothiophene Organometallics Vol 20,1049069-1049069頁 2001/07/01
論文	{(h5-C5Me5)Fe}2(m-H)2(m-h2:h2-H2SitBu2)a Versatile Precursor for Bimetallic Active Species Organometallics Vol 20,275546-275546頁 2001/07/01
論文	Novel trinuclear trihydride complexes of ruthenium having a triply bridging borylene ligand, {(eta(5)-C5Me5)Ru}(3)(mu-H)(3)(mu(3)-BX) (X = H, CN, OMe, OEt). Synthesis, structure determination, and reaction with benzothiophene 20 (23),4772-4774頁 (共著) 2001/11/01
論文	Synthesis, structures, and reactions of coordinatively unsaturated trinuclear ruthenium polyhydrido complexes, [{Ru(C5Me5)}(3)(mu-H)(6)](Y) (Y = BF4, CF3SO3, 1/2(SO4), C6H5CO2, CH3CO2, B(C6H5)(4), PF) and [{Ru(C5Me5)}(3)(mu-H)(3)(mu(3)-H)(2)] 78 (1),67-87頁 (共著) 2005/01/01
論文	Synthesis Structures and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes [{Ru(C5Me5)}3{m-H}6](Y) (Y = BF4 CF3SO3 1/2(SO4) C6H5CO2 CH3CO2 B(C6H5)4 PF6) and [{Ru(C5Me5)}3(m-H)3(m3-H)2] Bull. Chem. Soc. Jpn Vol 78,67-87頁 2005/07/01
論文	Electrolytic behavior and application to lithium batteries of monofluorinated dimethyl carbonate 177 (44989),299-303頁 (共著) 2006/01/01
論文	Electrolytic behavior and application to lithium batteries of monofluorinated dimethyl carbonate Solid State Ionics Vol 177,299-303頁 2006/07/01
論文	Theoretical Study on the Stereoselectivities ofthe Wittig Olefination Reaction ACADEMIC REPORTS Fac. Eng. Tokyo Polytech. Univ Vol 29,67-87頁 2006/07/01
論文	Theoretical Study of Electronic Substituent Effectin Fluorine-Containing Sydnones ACADEMIC REPORTS Fac. Eng. Tokyo Polytech. Univ 30,59-65頁 (共著) 2008/03/01
論文	Chirality and molecular dynamics of smectic compound studied by C-13-NMR spin-lattice relaxation time observation 364,129-135頁 (共著) 2008/04/01
論文	Chirality and Molecular Dynamics of Smectic Compound Studied by 13C-NMR Spin-Lattice Relaxation Time Observation Ferroelectrics 364,129-135頁 (共著) 2008/05/01
論文	A Density Functional Theory Study of the Alkali Metal Graphite Intercalation Compounds using Model Complexes 炭素 233,124-130頁 (共著) 2008/06/01
論文	Analysis of the α-Cyclodextrins Including p-Nitrophenol as a Guest Molecule with DFT Calculations 東京工芸大学紀要 31,83-90頁 (共著) 2009/03/01
論文	三次元表示を利用した化学教育ＩＴを活用した教育シンポジウム2008講演論文集 3,39-42頁 (単著) 2009/03/01
論文	Phase Transformation of Swollen Thermotropic Liquid Crystals Studied by X-Ray and H-2-NMR Measurements 509,743-750頁 (共著) 2009/04/01
論文	Phase Transformation of Swollen Thermotropic Liquid Crystals Studied by X-ray and 2H-NMR Measurements Mol. Cryst. Liq. Cryst. 509,743-750頁 (共著) 2009/05/01
論文	Several Molecular Orbital Computations for a Dinuclear Nickel(II) Complex J. Comput. Chem. Jpn. 8,87-92頁 (共著) 2009/06/01
論文	Theoretical Studies of the β-Hydrogen Elimination from π-Allyl Palladium Complexes J. Comput. Chem. Jpn. 8,73-80頁 (共著) 2009/06/01
論文	Molecular Dynamics in Smectic and Crystalline Phases Studied by C-13-NMR Spin Lattice Relaxation Time Observation 394,16-21頁 (共著) 2010/04/01
論文	Molecular Dynamics in Smectic and CrystallinePhases Studied by 13C-NMR Spin Lattice RelaxationTime Observation Ferroelectrics 394,16-21頁 (共著) 2010/04/01
論文	水環境健全性指標に基づく厚木近郊５河川の評価東京工芸大学紀要 33,86-93頁 (共著) 2011/03/01
論文	ヤマビルの化学分析東京工芸大学紀要 34,52-57頁 (共著) 2012/03/01
論文	化学の専門教育におけるGaussian09の活用ＩＴを活用した教育シンポジウム2011講演論文集 6,44-47頁 (単著) 2012/03/01
論文	Early-Late Heterobimetallic Complexes with a Ta-Ir Multiple Bond: Bimetallic Oxidative Additions of C-H_ N-H_ and O-HBonds Organometallics 13,4658-4661頁 (共著) 2012/06/01
論文	Early-Late Heterobimetallic Complexes with a Ta-Ir Multiple Bond: Bimetallic Oxidative Additions of C-H, N-H, and O-H Bonds 31 (13),4658-4661頁 (共著) 2012/07/01
論文	Bimetallic activation in the reaction of dinuclear ruthenium complexes with ethylene. J. Comput. Chem. Jpn. 3,125-130頁 (共著) 2012/08/01
論文	Bimetallic Activation of 2-Alkanones through Photo-Induced a-Hydrogen Abstraction Mediated by a DinuclearRuthenium Tetrahydride Complex Angew. Chem. Int. Ed. 6,1773-1776頁 (共著) 2013/01/01
論文	Bimetallic Activation of 2-Alkanones through Photo-Induced alpha-Hydrogen Abstraction Mediated by a Dinuclear Ruthenium Tetrahydride Complex Angewandte Chemie (International ed. in English) 52 (6),1773-1776頁 (共著) 2013/04/01
論文	Aluminum-Stabilized Low-Spin Iron(II) Hydrido Complexes of 1,4,7-Trimethyl-1,4,7-triazacyclononane 53 (10),5100-5108頁 (共著) 2014/05/01
論文	Aluminum-Stabilized Low-Spin Iron(II) Hydrido Complexes of 1_4_7-Trimethyl-1_4_7-triazacyclononane Inorganic Chemistry 10,5100-5108頁 (共著) 2014/05/01
論文	A Study on Zr−Ir Multiple Bonding Active for C−H Bond Cleavage. Inorganic Chemistry 13,6634-6654頁 (共著) 2014/06/01
論文	A Study on Zr-Ir Multiple Bonding Active for C-H Bond Cleavage 53 (13),6634-6654頁 (共著) 2014/07/01
論文	Green Metallic Luster on the Film of Safflower Red Pigment Extracted by a Traditional Method -Approach with Optical Measurements- 日本写真学会 Vol. 81, No. 1,pp.65-65-69頁 (共著) 2018/04/17
論文	Analysis of Gas Phase Reaction Pathways for InN Metal Organic Vapor Phase Epitaxy JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 51 (7),605-608頁 (共著) 2018/07/01
論文	Analysis of Gas Phase Reaction Pathways for InN Metal Organic Vapor Phase Epitaxy. J. Chem. Eng. Jpn. Vol. 51, No. 7,pp. 605-605-608頁 (共著) 2018/07/19
論文	ベニバナ生花を原料とする口紅「笹色紅」の伝統的な製法とその改良東京工芸大学工学部 41,86-89頁 (共著) 2018/12/01
論文	Lower Temperature Synthesis of Polymer Network from Liquid-Crystalline Polyesters with Titanium Alkoxide Catalysts 高分子学会 76,108-111頁 (共著) 2019/01/01
論文	21世紀型スキルを育成する工学分野における新しい情報教育の探索～博士前期課程「ビジネスコンピューティング特論」の実践～東京工芸大学工学部紀要 46 (1),24-28頁 (共著) 2023/12/25
その他	SYNTHESIS AND PROPERTIES OF (PI-ALLYL)PALLADIUM FORMATES AS INTERMEDIATES IN PALLADIUM-CATALYZED REDUCTIVE CLEAVAGE OF ALLYLIC ACETATES AND CARBONATES WITH FORMIC-ACID 10 (5),1221-1223頁 (共著) 1991/05/01
その他	{(η5-C5Me5)Fe}2(μ-H)2(μ-η2:η2-H2SitBu2), a Versatile Precursor for Bimetallic Active Species 20,2654-2656頁 (単著) 2001/04/01
その他	(304)メディア環境を利用した導入教育での課題解決型グループ学習(セッション87 リメディアル教育(補修教育)・導入教育III):: 学習目標の設定とデザイン能力の涵養工学・工業教育研究講演会講演論文集 2004 (0),603-604頁 (共著) 2004/04/01
その他	理論計算によるテトラアリールエテン類の構造解析と光異性化日本写真学会誌 67 (1),126-127頁 (共著) 2004/04/01
その他	Theoretical Study on the Stereoselectivities of the Wittig Olefination Reaction The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 29 (1),67-74頁 (共著) 2006/04/01
その他	Theoretical Study of Electronic Substituent Effect in Fluorine-Containing Sydnones. The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 30 (1),59-65頁 (共著) 2007/04/01
その他	ITを活用した低年次専門教育における教育法の改善 (ITを活用した動機付けや新しい教育の試み) ITを活用した教育シンポジウム講演論文集 2,53-56頁 (共著) 2008/03/01
その他	Analysis of the α-Cyclodextrins including p-Nitrophenol as a Guest Molecule with DFT Calculations. The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 31 (1),83-90頁 (共著) 2008/04/01
その他	錯体モデルを用いたアルカリ金属‐黒鉛層間化合物の密度汎関数法による解析炭素 2008 (233),124-130頁 (共著) 2008/06/01
その他	三次元表示を利用した化学教育--立体構造、軌道、および立体化学への理解を深めるために (ITを活用した教育法の研究/実践) ITを活用した教育シンポジウム講演論文集 3,39-42頁 (単著) 2009/03/01
その他	Several Molecular Orbital Computations for a Dinuclear Nickel(II) Complex Journal of computer chemistry, Japan 8 (1),87-92頁 (共著) 2009/12/01
その他	Theoretical Studies of the β-Hydrogen Elimination from π-Allyl Palladium Complexes Journal of computer chemistry, Japan 8 (1),73-79頁 (共著) 2009/12/01
その他	水環境健全性指標に基づく厚木近郊5河川の評価東京工芸大学工学部紀要 = The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 33 (1),86-93頁 (共著) 2010/04/01
その他	ヤマビルの化学分析東京工芸大学工学部紀要 = The Academic Reports, the Faculty of Engineering, Tokyo Polytechnic University 34 (1),52-57頁 (共著) 2011/04/01
その他	化学の専門教育におけるGaussian09の活用 ITを活用した教育シンポジウム講演論文集 6,44-48頁 (単著) 2012/03/01
その他	Bimetallic Activation in the Reaction of Dinuclear Ruthenium Complexes with Ethylene Journal of Computer Chemistry, Japan 11 (3),125-130頁 (共著) 2012/04/01
その他	液晶性ポリエステルからなるポリマーネットワーク形成反応の低温化高分子論文集 (共著) 2018/04/01
その他	伝統的手法で抽出されたベニバナ色素膜の緑色金属光沢について:─光学的手法による検討─ 日本写真学会誌 81 (1),65-69頁 (共著) 2018/04/01
その他	ベニバナ生花を原料とする口紅「笹色紅」の伝統的な製法とその改良東京工芸大学工学部紀要(Web) 41 (1 (Dec)),86‐89 (WEB ONLY) (共著) 2018/12/25
その他	金属元素を含まない材料から生じる金属光沢の光学特性東京工芸大学工学部紀要(Web) 43 (1 (June)) (共著) 2020/04/01